Despite Mario Gomez’ first half goal, the Australians rallied in the second half to topple the home side, Germany 2-1.
A neatly-taken goals by Blackpool's David Carney, the 1000th goal conceded by Germany, and a penalty from Luke Wilkshire, consigned the Germans to defeat.
A late goal from Asamoah Gyan earned Ghana a 1-1 draw with England at Wembley.
Recent Liverpool signing Andy Carroll put the Three Lions ahead just before the interval but the English were denied a victory over the World Cup quarter-finalists when Sunderland forward Gyan curled in a fine goal for the Africans.
France and Croatia played out a scoreless draw at the Stade de France, in a rematch of the 1998 World Cup semi-final which saw Croatia coach Slaven Bilic controversially have his opposite number Laurent Blanc sent off.
World Cup semi-finalist Uruguay overcame a late comeback to grab an entertaining 3-2 win over Ireland.
A Shane Long headed effort cancelled out Diego Lugano’s goal but then strikes from Edinson Cavani and Abel Hernandez put the Uruguayans 3-1 ahead.
A Keith Faley penalty gave the Irish a chance but the Uruguayans held on.
Qatar grabbed a surprise 1-1 result against Russia. They lead through Mohamed Kasoula, but were denied a famous victory when Tottenham striker Roman Pavlyuchenko equalised with a shot that Qatari goalkeeper Meshal Mubarak got a hand to.
Former World Cup champions Italy beat Ukraine 2-1 in Kiev thanks to goals from Giuseppe Rossi and Alessandro Matri.
Greece was held to 0-0 draw by Poland in Piraeus despite a handful of scoring opportunities falling their way in each half.
Portugal beat Finland in Aviero thanks a brace from debutant Rúben Micael.
Canada edged out Belarus at a near-empty stadium in Antalya in Turkey courtesy of a 58th minute strike from Houston Dynamo defender Andre Hainault.
A Michael Krohn-Dehli winner saw Denmark come out on top against Slovakia. Denmark drew first blood after an own goal from Slovakia’s Kornel Salata although the Slovakians drew level Filip Holosko but it was the Brondby midfielder who had the last laugh for the Danes.
A solitary goal separated Bulgaria and Cyprus with the Bulgarians coming out on top courtesy of a contentious Martin Petrov goal.
In Asia, China resoundingly defeated Honduras by three goals thanks to a from goal from Huang Bowen, and a Yang Xu double – all of which were set up by Schalke midfielder Hao Junmin.
In Latin America, Ecuador were held 0-0 by Peru in The Hague, Netherlands.
The Peruvians, who were reduced to 10 men, managed to hold on after goalkeeper Salomon Libman’s saved Ecuador captain Walter Ayovi's penalty in the first half.
A Matias Fernandez free-kick and Jean Beausejour strike saw Chile beat Colombia 2-0.
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